The song is from season 3 episode 1 of MLP:FiM.
♫ Lyrics for the song:
----------
[Twilight Sparkle]
I was prepared to do my best
Thought I could handle any test
For I can do so many tricks
But I wasn’t prepared for this
Levitation would have been a breeze
Facts and figures I recite with ease
Twilight Sparkle: The square root of five hundred and forty-six is twenty-three point three six six six four two eight nine one zero nine.
Teacher: She is correct!
[Twilight Sparkle]
I could ace a quiz on friendship’s bliss
But I wasn’t prepared for this
Will I fail, or will I pass?
I can’t be sure...
[Spike]
She can’t be sure...
[Twilight Sparkle]
My mind is sharp, my skills intact
My heart is pure...
[Spike]
Her heart is pure...
[Twilight Sparkle]
Oh, I’ve taken my share of licks
I’ve made it through the thin and thick
But no I
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